Graphene Flagship researchers at RWTH Aachen University and ONERA-CNRS, in collaboration with researchers at the Peter Grunberg Institute, the University of Versailles and Kansas State University, have reported a significant step forward in growing monoisotopic hexagonal boron nitride at atmospheric pressure for the production of large and very high-quality crystals.
This finding paved the way to a series of exciting developments, including the discoveries of exotic effects such as magic-angle superconductivity and proof-of-concept demonstrations of sensors with unrivalled sensitivity.
Until now, the most widely used hBN crystals came from the National Institute of Material Science in Tsukuba, Japan. These crystals are grown using a process at high temperatures (over 1500°C) and extremely high pressures (over 40,000 times atmospheric pressure).
New Method Overcomes Limitations of hBN Growth Method
However, this hBN growth method comes with some limitations. Among them is the small crystal size, which is limited to a few 100 μm, and the complexity of the growth process. This is suitable for fundamental research, but beyond this, a method with better scalability is needed.
Now Graphene Flagship researchers tested hBN crystals grown with a new methodology that works at atmospheric pressure, developed by a team of researchers led by James Edgar at Kansas State University, US. This new approach shows great promise for more demanding research and production.
The method for growing hBN at atmospheric pressure is indeed much simpler and cheaper than previous alternatives and allows for the isotopic concentration to be controlled. In addition, Graphene Flagship partners in ONERA-CNRS, France, led by Annick Loiseau, carried out advanced luminescence measurements. Both measurements indicated high isotope purity and high crystal quality.
Creating High-quality hBN
However, the strongest evidence for the high hBN quality came from transport measurements performed on devices containing graphene sandwiched between monoisotopic hBN. They showed equivalent performance to a state-of-the-art device based on hBN from Japan, with better performance in some areas.
Mar García-Hernández, work package leader for Enabling Materials, adds: "
When graphene is encapsulated by hBN, it reveals its intrinsic properties. This makes hBN an essential material to integrate graphene into current technologies and demonstrates the importance of devising new scalable synthetic routes for large-scale hBN production. This work not only provides a new and simpler path to produce high-quality hBN crystals on a large scale, but it also enables the production of monoisotopic material, which further reduces the degradation of graphene when encapsulated by two layers."
Andrea C. Ferrari, science and technology officer of the Graphene Flagship and Chair of its management panel, adds: "
This is a nice example of collaboration between the EU and the US, which we fostered via numerous bilateral workshops. Devising alternative approaches to produce high-quality hBN crystals is crucial to enable us to exploit the ultimate properties of graphene in opto-electronics applications. Furthermore, this work will lead to significant progress in fundamental research."
Source: RWTH Aachen University