TAGS: Sustainability / Natural Solutions Additives for Packaging Polymer Reinforcement
Nylon-6 is a tough, non-biodegradable plastic that cannot be recycled by conventional methods. A new way has now been introduced by a team from the U.S. in the journal Angewandte Chemie International Edition. A team led by Yosi Kratish and Tobin J. Marks at Northwestern University and the National Renewable Energy Laboratory has now developed a new, efficient catalytic process for recycling Nylon-6.
With an easily accessible lanthanum trisamido catalyst, Nylon-6 can be depolymerized highly selectively, nearly quantitatively, with no solvent, and at moderate temperatures to recover the monomer, ε-caprolactam. The monomers are removed sequentially from one polymer end, just like unthreading pearls from a chain.
Depolymerization with 95% Selectivity
Nylon-6 is depolymerized to ε-caprolactam with over 95% selectivity and over 90% yield—without solvents or toxic chemicals and at the comparably mild temperature of 240 °C. Admixtures of polyethylene, polypropylene, or polyethylene terephthalate do not interfere.
The team's success rests on a catalyst based on commercially available trisamido complexes of the rare earth metals. A lanthanum complex demonstrated the highest catalytic activity. Experimental data and computations suggest a novel mechanism for the reaction. In the first step, a hydrogen ion is removed from a terminal amide N–H bond and the catalyst is covalently bound to the polymer.
Subsequently, the ε-caprolactam units are split off the end of the chain one by one in a backbiting process. Industrially, the variant Nylon-6 is made through a ring-opening polymerization of ε-caprolactam on a scale of 5 million tons a year. The market volume is projected to reach 21.5 billion dollars by 2026. The heaps of trash are growing correspondingly, increasing the danger to the environment and our health. In addition, the production of Nylon-6 has a large CO
2 footprint.
The monomer, ε-caprolactam, is made from fossil-based raw materials in a costly, multistep process. Its reclamation would conserve resources and save on production costs and energy. There is thus a high demand for a circular economy for Nylon-6.
Related Read: Polyamide Performance Developments : 2022 Trends & Opportunities
Nylon is the fabric from which stockings are made. It is also the material of choice for many applications in areas including automobile manufacturing, packaging, infrastructure, textiles, and fishing. Its advantageous properties, such as elasticity, chemical resistance, high tensile strength, and high abrasion resistance get in the way of its biodegradability. Abandoned nylon fishing nets, for example, account for about 10% of the plastic waste in the oceans.
Source: Phys Org