New Test Facility to Produce Carbon Black Powder from Carbon Dioxide

At Karlsruhe Institute of Technology (KIT), the NECOC research project is aimed at building a unique test facility for active reduction of atmospheric carbon dioxide (CO₂).

This facility will convert CO₂ contained in ambient air into highly pure carbon black powder that can be used as a resource in industry. Project partners are INERATEC GmbH, a spinoff of KIT, and Climeworks, a spinoff of ETH Zurich. The research project, scheduled for a duration of three years, is funded with a total of EUR 1.5 million by the Federal Ministry for Economic Affairs and Energy (BMWi).

Global Efforts to Reduce Greenhouse Gas Emissions

With the Paris climate agreement of 2015, the global community has committed itself to limit global warming to below 2°C by the end of the century. To reach this goal, however, global efforts to reduce greenhouse gas emissions will have to be complemented by solutions for removing already emitted CO₂ from the atmosphere. “Our project approach consists of removing CO₂ from the atmosphere and converting it into carbon black, i.e. highly pure carbon in powder form,” says Professor Thomas Wetzel of the Institute of Thermal Process Engineering (TVT) and Head of the KALLA Karlsruhe Liquid Metal Laboratory of the Institute for Thermal Energy Technology and Safety. “In this way, a hazardous greenhouse gas will be converted into a raw material for high-tech applications. Carbon black can be used in electronics, printing, or construction.”

Test Facility Combines Several Process Steps

The test facility to be set up within the NECOC research project will combine the following process steps: By means of an adsorber, CO₂ is first captured from ambient air (direct air capture, DAC). Together with renewable hydrogen, it is then converted into methane and water in a microstructured reactor.

The methane produced serves as a carbon carrier in the downstream process and is passed into a bubble reactor filled with liquid tin. In the ascending methane bubbles, a pyrolysis reaction takes place, by means of which methane is decomposed into its constituents. These are, on the one hand, hydrogen, that is directly fed back to methanation and, on the other hand, solid carbon in the form of microgranular powder, i.e. carbon black.

All process steps have already been studied and developed up to the laboratory scale by the researchers involved. “We know the individual modules well,” says Dr. Benjamin Dietrich (TVT), project coordinator of NECOC. ”However, they have never been realized together in an integrated facility so far. This is the first time worldwide. Skillful integration of the process modules and correct process conduct will be decisive for the energy efficiency of the process and the quality of the carbon black product.“ The major advantage over previously proposed concepts to reduce atmospheric CO₂, such as carbon capture and storage methods (CCS) to store CO₂ in deep rock layers, consists in this end product. “Solid carbon is far less difficult to handle than CO₂ and can even be used as a resource. So far, carbon black has been produced mainly from fossil petroleum. That is why our process represents a technological approach for a sustainable future in several respects. It combines the direct contribution to solving the climate problem with a process for post-fossil resource supply.”

Source: KIT